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Q.

Which of the comparison regarding Zn, Cd, Hg islare incorrect ?
(l) ZnCl2 is ionic whereas CdCl2 and HgCl2 are covalent
(II) Zn and Cd dissolves in dilute acid (HCl) liberating H2 but Hg can not
(III) Zn and Cd forming with ppt. of Zn(OH)2 and Cd(OH)2 but Hg forms coloured ppt. of Hg(oH)2
(IV) all form A22+ type ion

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a

only III

b

I, III, IV

c

I and III

d

all of these

answer is B.

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Detailed Solution

ZnCl2 , CdCl2 , HgCl2 all are covalent. Zn and Cd form white ppt. of Zn(OH)2 and Cd(OH)2 but Hg form HgO on adding NaOH. Zn(OH)2  further dissolves on adding excess NaOH.

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