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Q.

Which of the following alcohols is expected to have minimum boiling point?

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a

2-Butanol

b

1-Butanol

c

2-Methyl-2-propanol

d

1-Pentanol

answer is C.

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Detailed Solution

2-Methyl-2-propanol alcohols is expected to have minimum boiling point 

The boiling point of a liquid is the temperature at which the ambient pressure and the vapour pressure are equal.

Increasing branching causes lowering of boiling point.

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