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Q.

Which of the following alcohols is expected to have the lowest pKa value?

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a

2,2,2-Trifluoroethanol
 

b

2-Chloroethanol

c

2-Fluoro ethanol
 

d

 Ethanol
 

answer is C.

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Detailed Solution

Given data:
It is given to identify the alcohol that is expected to have the lowest pKa value.
Explanation:

2,2,2-Trifluoroethanol is the organic compound which has the formula CF3CH2OH. Also known as TFE or trifluoromethyl alcohol, this colorless, water-miscible liquid has a smell reminiscent of ethanol.

Since fluorine has a stronger influence than chlorine, 2,2,2-trifluoroethanol has the lowest pKa value. 

Hence, the correct option is option (C) 2,2,2-Trifluoroethanol.

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