Q.

Which of the following amine does not react with Hinsberg's reagent at room temperature?

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a

CH3CH2NH2

b

All of these

c

CH3CH23N

d

CH3CH22NH

answer is C.

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Detailed Solution

Only the 1 and 2 amines can react with the Hinsberg reagent because the hydrogen in both of them is acidic and is replaced during the reaction, but the 3 amine in benzene sulphonyl chloride does not contain replaceable hydrogen. As a result, the 3amine triethyl amine C2H53N cannot react with the Hinsberg reagent.

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