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Q.

Which of the following amines can be prepared by Gabriel-phthalimide reaction.
i) Triethyl amine  ii) n-butyl amine  iii) t-butyl amine  iv) neo pentyl amine  v) Aniline

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a

Only ii

b

Only ii and v

c

Only ii,iii,iv

d

i,ii,iii,iv and v . 

answer is A.

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Detailed Solution

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Only 10 aliphatic amines are prepared. 3, 4 cannot be prepared because of steric hinderence.

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