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Q.

Which of the following anions does not interfere in the systematic analysis of salt analysis?

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a

Fluoride

b

Borate

c

Thiosulphate

d

Phosphate

answer is D.

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Detailed Solution

Thiosulphate anions does not interfere in the systematic analysis of salt analysis

Since interfering radicals are insoluble in alkaline media, this has an impact on the solubility product of cations and results in incomplete precipitation in group III and premature precipitation in group IV and V. It is clear from the aforementioned explanation that interfering radicals start to cause problems with group III and below.

Hence option D is correct

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