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Q.

Which of the following aqueous solutions will have maximum vapor pressure?

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a

An aqueous solution of I2(s) in water having mole fraction of Iodine equal to 0.01.

b

0.02 M BaCl2

c

20% w/w glucose solution

d

0.05 M K4 [Fe(CN)6]

answer is B.

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Detailed Solution

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  • Molarity of particles for
  • K4 [Fe(CN)6 ]  0.05 × 5= 0.25 M BaCl2  0.02 × 3 = 0.06 M Glucose  1.11 M  XI2 = 0.01 or 0.55 M
  • From above data it is clear that [BaCl2] has least value. 
  • So, it exerts maximum vapor pressure. 
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