Q.

which of the following are aromatic compounds?

i)Question Image

ii) Question Image

iii) Question Image

iv) Question Image

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a

(i) and (ii)

b

(i) ,(ii) and (iii)

c

(iii) and (iv)

d

(ii) and (iv)

answer is C.

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Detailed Solution

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Aromaticity is due to the 

  • Planarity
  • Complete delocalization of the pi electrons in the ring
  • Presence of (4n+2 )πelectrons in the ring

(1) Napthalene 

Question Image

n=2 

Huckel'rule :(4n+2 )πelectrons

=4(2) +2 πelectrons = 10πelectrons

(2) Benzene :

Question Image

n=1

Huckel'rule :(4n+2 )πelectrons

=4(1) +2 πelectrons = 6πelectrons

so these two molecules are Aromatic.

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