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Q.

Which of the following are correct statements?

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a

Spontaneous adsorption of gases on solid surface is an exothermic process as entropy decreases during adsorption 

b

Formation of micelles takes place when temperature is above Kraft Temperature (TK) and concentration is above critical micelle concentration (CMC)

c

A colloid of Fe(OH)3  is prepared by adding a little excess (required to completely precipitate Fe3+ ions as Fe(OH)3 of NaOH in FeCl3 solutions 

d

According to Hardy-Schulze rules the coagulation (flocculating) value of Fe3+ ion will be more than Ba2+ or Na+

answer is A.

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Detailed Solution

(a)G =H -TS <0

S <0 so H is always negative

(b)If FeCl3 is added to excess of hot water, a positively charged sol of
hydrated ferric oxide is formed due to adsorption of Fe3+ ions. However,
when ferric chloride is added to NaOH a negatively charged sol is
obtained with adsorption of OH- ions.
(c) The sol. will be negative charge

(d) More the charge on cation ,higher the coagulating power.

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