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Q.

Which of the following are true for the first order reaction

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a

t1516=3t34

b

t78=2t34

c

t3/4=2t1/2

 

d

t15/16=4t1/2

answer is A, B.

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Detailed Solution

According to hit and trial method for first order reaction,

t=2.303Klogaa-x

t12=2.303Klogaa-a2

t12=2.303Klog2aa

t12=2.303Kx0.3010

t12=0.693K

t12t34=2.303Klog 12.303Kxlog 2

t12t34=12t34=2t12

t1516=2.303Klogaa-15a16

=2.303kloga16a-15a16

=2.303K4log2

=4x0.693K

t1516t11=2.303Kx4x log22.303Kxlog2

t1516=4tt2

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