Which of the following arrangements with respect to their reactivity in nucleophilic addition reaction is correct?

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benzaldehyde < acetophenone < p-nitrobenzaldehyde < p-tolualdehyde

acetophenone < benzaldehyde < p-tolualdehyde < p-nitrobenzaldehyde

acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde

p-nitrobenzaldehyde < benzaldehyde < p-tolualdehyde < acetophenone

answer is C.

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Detailed Solution

The rate of nucleophilic addition decreased due to steric crowding around carbonyl carbon & increased by the electron withdrawing group. If the steric crowding is same hence, the reactivity towards nucleophilic addition will be

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