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Which of the following base does not react with B₂ $H_{6}$ to give [BH₂(Base)₂]⁺ [BH₄]^– ?

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NH₃

CH₃NH₂

(CH₃)₂NH

(CH₃)₃N

answer is D.

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Detailed Solution

B₂H₆reacts with primary(1º) and secondary(2º) amine and form an ionic compound and gives unsymmetrical cleavage of diborane. However with tertiary(3º) amine, B₂H₆ shows it's symmetrical cleavage and forms an adduct as:-

B₂H₆+2N(CH₃)₃⟶2BH₃.N(CH₃)₃

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