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Q.

Which of the following can exhibit geometrical isomerism (M stands for a metal, and a and b are achiral ligands)?

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a

Ma2b2

b

Ma2b4

c

Ma5b

d

Ma6

answer is A, B.

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Detailed Solution

Geometrical isomerism can be seen in square planar Ma2b2 and octahedral Ma4b4.

They come in both cis and trans forms. In the complexes Ma5 and Ma6, geometrical isomerism is not possible.

The correct answer is a, b.

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