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Q.

Which of the following cannot convert 1-decanol to decanoic acid ?

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a

Jones reagent

b

acidified K2Cr2O7  

c

 acidified KMnO4

d

Pyridiumchloro chromate

answer is C.

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Detailed Solution

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Pyridinium chlorochromate (PCC) is a milder version of chromic acid. PCC oxidizes 1o alcohols one rung up the oxidation ladder, turning primary alcohols into aldehydes and secondary alcohols into ketones. Unlike chromic acid, PCC will not oxidize aldehydes to carboxylic acids

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