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Which of the following cannot give carbyl amine test
A) Aniline
B) N-methylaniline
C) N, N-dimethyl aniline
D) O-toluidine
E) p-anisidine
F) Methanamine
G) Acetamide
H) Cyclohexanamine
I) Dimethyl amine
J) N-ethyl-N-methyl- 2-propanamine

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B, C, G, I, J

A, B, C, D, E,

B, C, E, G, I, J

B, C, I, J

answer is A.

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Detailed Solution

$R - {NH}_{2} (or) Ar - {NH}_{2} + {CHCl}_{3} + 3 KOH (alc) \overset{Δ}{\to} R - NC (or) Ar - NC + 3 KCl + 2 H_{2} O$

$R - NC (or) Ar - NC$ is foul smelling.

This is a test to identify any $1^{o}$ alkyl (or) $1^{o}$ aryl amine

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