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Q.

Which of the following carbohydrates has a glycosidic linkage ? 
 

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a

Fructofuranose 
 

b

Glucopyranose 
 

c

Maltose 
 

d

β-D-Fructose 
 

answer is C.

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Detailed Solution

The problem is asking about a hydrocarbon with the formula C6H8 that undergoes catalytic hydrogenation and ozonolysis to form a product. The two moles of methane dicarbaldehyde suggest a certain structural feature.

Looking at the options:

  • Option A (Hexa - 1,3,5-triene): This suggests a triene structure with alternating double bonds. However, the ozonolysis of this molecule wouldn't produce the same product as described in the question.
  • Option B (1-methylcyclopropene - 1,4-diene): This is a possibility, but it doesn't fit the described reactions.
  • Option C (Cyclohexa - 1,3-diene): This is also a potential candidate because it has conjugated double bonds, and catalytic hydrogenation could lead to an addition of hydrogen. Its ozonolysis could give two moles of aldehyde.
  • Option D (Cyclohexa - 1,4-diene): This option could also be valid, but it doesn't have the ideal conjugation required to match the ozonolysis pattern.

The correct answer is C (Cyclohexa - 1,3-diene) because it fits the reaction mechanism described.

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