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Q.

Which of the following carbonium ion is stabilised by hyperconjugation ?

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a

$C H_{3} = C C l_{2} - \overset{\oplus}{C} H_{2}$

b

$C H_{3} - \overset{\oplus}{C} H - C H_{3}$

c

$C H_{2} = C H - \overset{\oplus}{C} H_{2}$

d

$C H_{2} = C H^{\oplus}$

answer is D.

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Detailed Solution

Greater the no. of alkylic(or alpha) hydrogens greater is the no. of hyper conjugated structure and more is the stability.

Alpha-Hs are more in option(D) which is secondary carbocation.

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Which of the following carbonium ion is stabilised by hyperconjugation ?