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Q.

Which of the following cations will have minimum flocculation value for the arsenious sulphide sol?

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a

Na+

b

Mg2+

c

Ca2+

d

Al3+

answer is D.

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Detailed Solution

The coagulation or flocculation value of an electrolyte is the amount of the electrolyte that must be added to one litre of a colloidal solution in order to fully coagulate the solution. The amount of electrolyte needed to coagulate a specific amount of coagulating ion decreases as the valency of the coagulating or flocculating ion increases. Thus, trivalent cations Al3+ are much more effective than divalent Ba2+ cations, which in turn are more successful than monovalent Na+ cations for coagulation of negatively charged arsenious sulphide solution. So, the arsenic sulphide solution's flocculating value is in the following order: Na+>Ca2+=Mg2+>Al3+

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Which of the following cations will have minimum flocculation value for the arsenious sulphide sol?