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Which of the following chloride is most unstable?

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a

${TlCl}_{3}$

b

${BCl}_{3}$

c

${Al}_{2} {Cl}_{6}$

d

${AlCl}_{3}$

answer is D.

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Detailed Solution

The order of elements in IIIA group is Boron, Aluminium, Gallium, Indium and Thallium.
While moving down the group the tendency to form +1 oxidation state increases and the tendency to form +3 oxidation state decreases. So, thallium is more stable in +1 oxidation state.
Hence, ${TlCl}_{3}$ is the most unstable.

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