Which of the following combinations are correct for a binary solution, in which the solute as well as solvent are liquid?

CH₃COCH₃ and CHCl_3; it shows negative deviation. In negative deviation, $∆{\mathrm{H}}_{\mathrm{solution}}<0 \mathrm{and} ∆{\mathrm{V}}_{\mathrm{solution}}<0$

H₂O and CH₃OH_; it shows positive deviation. In positive deviation, $∆{\mathrm{H}}_{\mathrm{solution}}>0 \mathrm{and} ∆{\mathrm{V}}_{\mathrm{solution}}>0$