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Q.

Which of the following combinations regarding True ('f) and False (F) nature of following statement is correct? 

Statement-I: pH of water at any temperature will be 7. 

Statement-2: Acid dissociation constant of water at 298 K is equal to 1014

Statement-3: For any aqueous acid solution (pH+ pOH) will be equal to 14 at 298 K. 

Statement-4: Degree of dissociation of water at 308 K will be greater than 1.6×107%.

Statement-5: On increasing' dilution extent of dissociation of MCI will increase.

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a

TFT'l"I'

b

FFTTF

c

FT'TFF

d

TTFFT

answer is D.

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Detailed Solution

3)For any aqueous acid solution (pH+ pOH) will be equal to 14 at 298 K. Here, the solution is highly acidic.

4) pH of water changes with temperature because degree of dissociation and hence, kw also changes.

kaH2O298K=1014100018=1.8×1016

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