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Q.

Which of the following complex compound does not show stereoisomerism ?

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a

Zn(SCN)H2O(gly)

b

PdBrClNO2NH3

c

PtBrH2O(en)

d

Co(acac)3

answer is D.

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Detailed Solution

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PdBrClNO2NH3Hyb. of Pd2+:dsp2 complex has plane of symmetry hence does not exhibit optical isomerism. But it exhibits geometrical isomerism and number of geometrical isomers = 3.
 The complex : [ Zn(SCN)H2O (gly)] exhibits optical isomerism 
Number of stereoisomers = 2
 

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 Hybridization of zinc :sp3
 The complex : [ Co(acac)3 exhibits optical isomerism 
Number of stereoisomers = 2
 

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 The complex PtBrH2O( en ) does not exhibit geometrical and optical isomerism, because it contains plane of symmetry.

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