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Q.

Which of the following complex compound shows optical isomerism?

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a

CuNH342+

b

Zn(Cl)42-

c

CrC2O432-

d

Co(CN)63-

answer is C.

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Detailed Solution

Given:- It is given to find the complex compound showing optical isomerism.

Explanation:-

The mixture CrC2O432- shows optical isomerism because its mirror image is not superimposable. It is the complex of the type M(AA)3n+. On the Cr atom, there are three symmetrical bidentate ligands (also known as oxalate ligands). The compound comes in the forms of d and l isomers and is optically active.

 

Therefore, (C) is the appropriate response. CrC2O432-

 

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