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Q.

Which of the following complex compounds is not colored?

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a

Na2[CuCl4]

b

Na2[CdCl4]

c

K3[Fe(CN)6]

d

K4[Fe(CN)6]

answer is B.

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Detailed Solution

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  • Oxidation state of Cd in Na2[CdCl2] is +2 and its outer electronic configuration becomes 4d10
  • Due to filled d-orbitals, there is no d-d transition taking place. 
  • Hence, the compound does not show any color.
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