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Q.

Which of the following complex compounds is not coloured 

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a

 K4[Fe(CN)6]

b

K3[Fe(CN)6]

c

Na2[CdCl4

d

 Na2[CuCl4

answer is B.

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Detailed Solution

 Na2[CdCl4] Cd : 4d10 5s2

           Cd+2 : 4d10

Because there is no opportunity for d-d transition in Cd2+ ion, it lacks color.

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