Q.

Which of the following complex does not show geometrical isomerism?

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a

Pt( gly )2

b

CoNH34Cl2+

c

Cr(en)33+

d

CoNH33NO23

answer is C.

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Detailed Solution

Cr(en)33+ will have 2 optical isomers but have no geometrical isomers. The complex Cr(en)33+ contains no element of symmetry.

 This complex optically active and resolved in d and l isomers.

Hence correct option is C.

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