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Q.

Which of the following complex ion has tetrahedral arrangement?

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a

${[{AuCI}_{4}]}^{-}$

b

${[{PbCl}_{4}]}^{2 -}$

c

${[{FeCl}_{4}]}^{-}$

d

All are having tetrahedral structure

answer is C.

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Detailed Solution

The $[F e C l_{4}]^{-}$ ion is arranged in a tetrahedron.
$[F e C l_{4}]^{-}$ is ${sp}^{3}$ hybridized with five unpaired electrons and a tetrahedral structure.

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