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Which of the following complex species does not involve inner orbital hybridization?

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[Co(NH₃)₆]³⁺

[Cr(NH₃)₆]³⁺

[CoF₆]^3-

[Fe(CN)₆]^3-

answer is C.

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Detailed Solution

[CoF₆]³⁻is a outer orbital complex ion. It involves outer orbital hybridization. It has sp³d²− hybridization because F⁻ is a weak ligand.

CN⁻,NH₃ will show inner orbital hybridization as they are strong field ligands.

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