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Q.

Which of the following complex species does not involve d2sp3 hybridization?
 

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a

Co(NH3)63-

b

Fe(CN)63-

c

CoF63-

d

Cr(NH3)63+

answer is A.

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Detailed Solution

 d2sp3 hybridization happens in an inner d-orbital complex. In an inner d-orbital complex strong field ligand is present. 

CoF63- is a weak field ligand, preventing inner orbital hybridization.
as the powerful field ligands, CNNH3 will exhibit inner orbital hybridization. 

Hence the correct answer is CoF63-

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