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Q.

Which of the following complex will show largest splitting of d-orbitals

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a

${[Fe {(SCN)}_{6}]}^{- 3}$

b

${[{FeF}_{6}]}^{- 3}$

c

${[Fe {(CN)}_{6}]}^{- 3}$

d

${[Fe {({NH}_{3})}_{6}]}^{+ 3}$

answer is C.

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Detailed Solution

CN^- is a S.F.L which causes greater d-orbital splitting.

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