Which of the following complexes are heteroleptic?

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${[Fe {({NH}_{3})}_{4} {Cl}_{2}]}^{+}$

$[Co {({NH}_{3})}_{4} {Cl}_{2}]$

${[Mn (CN)_{6}]}^{4 -}$

${[Cr {({NH}_{3})}_{6}]}^{3 +}$

answer is B, D.

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Detailed Solution

${[Fe {({NH}_{9})}_{4} {Cl}_{2}]}^{+}$ and $[Co {({NH}_{3})}_{4} {Cl}_{2}]$ are heteroleptic complexes because it contains more than one type of ligand.

Hence, options B and D are correct.

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