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Which of the following complexes has the highest stability constant at 298 K?

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[CdCl₄]^2–

[CdBr₄]^2–

[Cdl₄]^2–

[Cd(CN)₄]^2–

answer is D.

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Detailed Solution

[Cd(CN)₄] At 298 K, complex 2 has the highest stability constant.
Cyano and ammine complexes are far more stable than halide ion complexes.
This is because NH₃ and CN are more powerful Lewis bases.

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