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Q.

Which of the following complexes is inner orbital complex or low spin or spin paired complex

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a

${[{CoF}_{6}]}^{3 -}$

b

${[Mn (CN)_{6}]}^{3 -}$

c

${[{NiCl}_{4}]}^{2 -}$

d

${[{MnCl}_{6}]}^{3 -}$

answer is D.

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Detailed Solution

${{[Mn(CN)}_{6}]}^{3-}$ is inner orbital complex in which Mn⁺³ undergoes d²SP³ hybridization.

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