Q.

Which of the following complexes is least likely to exist?

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a

Zn(OH)42

b

Hg(OH)42

c

HgI42

d

PtCl42

answer is A.

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Detailed Solution

Since Hg2+ is soft while OHis hard and soft acids form more powerful complexes and Hard acids form more powerful acid-base complexes with bases is least exist.

So, option A is correct answer.

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Which of the following complexes is least likely to exist?