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Q.

Which of the following complexes show ionization isomerism ?

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a

Cr(en)3Cl3

b

CrNH36Cl3

c

CoBrNH35SO4

d

K4Fe(CN)6

answer is D.

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Detailed Solution

Complex [CoBr(NH3)5SO4]] exhibits ionization isomerism.
This chemical switches  Br- and SO4-2 to produce two isomers with different ionizable components, which is why they show ionization isomerism. This cannot be done by other compounds.

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