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Q.

Which of the following compound gives red ppt. with Cu2Cl2/NH40H?

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a

CH3−C=C−CH=CH2

b

CH3−CH2−C≡CH

c

CH3−C≡C−CH3

d

CH3−CH2−CH=CH2

answer is B.

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Detailed Solution

Copper Acetylide is obtained as a red precipitate when a terminal alkyne is passed through an ammoniacal solution of cuprous chloride.

CH3−CH2−C≡CH
correct option is B. 

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