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Q.

Which of the following compound has/have effective atomic number equal to the atomic number of a noble gas?

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a

K[Co(CO)4] 

b

K2[Fe(CO)4] 

c

[Co(NH3)6]Cl2 

d

[CoCl3(H2O)3] 

answer is Ü, A, B, D.

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Detailed Solution

EAN=Z-X+Y Z=Atomic number of metal X=Number of electrons lost during the formation of the metal ion from its atom Y=Number of electrons donated by ligands

K[Co(CO)4]

EAN=Z-X+Y EAN=27+1+8=36

K2[Fe(CO)4]

EAN=Z-X+Y EAN=26+2+8=36

[CoCl3(H2O)3]

EAN=Z-X+Y EAN=27-3+12=36

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