Q.

Which of the following compound will give white ppt. with ammonical silver nitrate solution (Tollen's reagent)?

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a

PhNHOH

b

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c

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d

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answer is D.

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Detailed Solution

A silver nitrate and ammonia solution makes up Tollen's reagent.
With the help of tollen's reagent, terminal alkynes produce a precipitate that is white in colour.
Thus, 1-butyne and tollen's reagent react to produce white precipitate.

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