Which of the following compound would have significant intermolecular hydrogen bonding?

$\mathrm{HF}, {\mathrm{CH}}_3\mathrm{OH}, {\mathrm{N}}_2{\mathrm{O}}_4 , {\mathrm{CH}}_4$

Only HF and ${\mathrm{CH}}_3\mathrm{OH}$ form H-bonds.

A hydrogen atom attached to a highly electronegative atom, such as nitrogen, oxygen, or fluorine, experiences attraction to another neighboring highly electronegative atom, creating a hydrogen bond between the two polar groups. There is a lot of intermolecular hydrogen bonding between HF and ${\mathrm{CH}}_3\mathrm{OH}$.