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Q.

Which of the following compound would have significant intermolecular hydrogen bonding?

HF, CH3OH, N2O4 , CH4 

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a

HF, N2O4

b

 HF, CH4 , CH3 OH

c

HF, CH3OH

d

CH3 OH, CH4 

answer is C.

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Detailed Solution

Only HF and CH3OH form H-bonds.

A hydrogen atom attached to a highly electronegative atom, such as nitrogen, oxygen, or fluorine, experiences attraction to another neighboring highly electronegative atom, creating a hydrogen bond between the two polar groups. There is a lot of intermolecular hydrogen bonding between HF and CH3OH.

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