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Q.

Which of the following compounds does not react with NaHSO3 ?

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a

CH3CHO

b

CH3COCH3

c

HCHO

d

C6H5COCH3

answer is B.

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Detailed Solution

Aldehydes form a crystalline salt upon addition of a 40% aqueous solution of sodium bisulfite, a white color ppt is formed.Ketones do not respond for this test.

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