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Q.

Which of the following compound(s) is/ are planar about nitrogen?

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a

NBF23

b

NSiH33

c

NSiH32BF2

d

N¨CH33

answer is A, B, C.

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Detailed Solution

 N(SiH3)3 is planar because in  N(SiH3)3 lone pair on N−atom is shifted to the blank d− orbitals of silicon (pπ−dπ overlapping).

In  N(SiH3)3​, Si has vacant d-orbital. Here, the dπ−pπ overlap along the N−Si bond.

Thus, nitrogen has trigonal planar shape.

NBF23 is also planer about nitrogen atom.

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