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Q.

Which of the following compounds may give white precipitate or turbidity with dilute HCl

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a

PbNO32

b

CH3COONa

c

AgNO3

d

Na2S2O3

answer is A, B, C.

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Detailed Solution

PbNO32AgNO3 and Na2S2O3 may give white precipitate or turbidity with dilute HCl.

Silver nitrate makes up the substance X A white turbidity of AgCl is created when it combines with dil.HCl. In the presence of dilute HCl, hydrogen sulfide and silver nitrate react to produce a black ppt of silver sulphide that is soluble in nitric acid.The reaction is having follows,

AgNO3+HClAgCl+HNO3,

2AgNO3+H2S dilHCl Ag2S+2HNO3

The sodium salt in question is sodium thiosulphate Na2S2O3. It gives white turbidity with dil.HClsolution. The reaction is having follows,

Na2S2O3+2HCl2NaCl+H2O+SO2+S

Hence, options A, B and C are correct.

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