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Q.

Which of the following compounds when treated with PCl5 does not produce POCl3?

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a

SO2

b

H2O

c

P4O10

d

NO2

answer is D.

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Detailed Solution

Reaction of SO2 with PCl5 is:

SO2+PCl5SOCl2+POCl3

Reaction with PCl5 with water is:

PCl5+H2OPOCl3+2HCl

Reaction of PCl3 with P4O10 is:

P4O10+6PCl510POCl3

Reaction of PCl5 with nitrogen dioxide.

PCl5+2NO2PCl3+2NO2Cl

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