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Which of the following compounds would exhibit coordination isomerism :

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$[Cr {(H_{2} O)}_{6}] {Cl}_{2}$

$[Cr {({NH}_{3})}_{6}] [Co (CN)_{6}]$

$[Cr (en)_{2}] {NO}_{2}$

$[Cr {(H_{2} O)}_{5}] {Cl}_{3}$

answer is B.

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Detailed Solution

Co-ordination isomerism is a form of structural isomerism in which the composition of the complexion varies. In a coordination isomer, the total ratio ligand to metal remains the same, but the ligand attached to specific metal ion change.

In B option ratio of metal to the ligand is the same and they can exchange their ligands (NH₃,CN).

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