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Q.

Which of the following concentrations of NH4+ will be sufficient to prevent the  precipitation of Mg(OH)2 from a solution which is 0.01 M  MgCl2 and 0.1 M NH3(aq) .  Given that: Ksp  of Mg(OH)2=2.5×1011  and Kb  for  NH3(aq)=2×10-5

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a

0.01 M 

b

0.04 M

c

0.001 M 

d

0.02 M 

answer is D.

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Detailed Solution

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Ksp=[Mg+2][OH]2

[OH]=2.5×10110.01=5×105

Ksp=[NH4+][OH][NH3]

So,[NH4+]=0.04 M

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