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Which of the following configuration will not exists in both high spin and low spin forms?

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a

d³

b

d⁸

c

Both in d³ and d⁸

d

d⁵

answer is C.

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Detailed Solution

If the outer electronic configuration of the central metal ion in a complex is d¹, d² or d³, then the complex is inner orbital complex irrespective of the strength of the ligand.
And if the outer electronic configuration of the central metal ion in a complex is d⁸, d⁹ or d¹⁰, then complex is outer orbital complex irrespective of the strength of the ligand.

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