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Q.

Which of the following does not has an optical isomer?

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a

[Co(en)(NH3)2Cl2]Cl

b

[Co(en)2Cl2]Cl

c

[Co(en)3]Cl3

d

[Co(NH3)3Cl3]

answer is C.

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Detailed Solution

Complex present in option-3 cannot have optical isomers due to presence of an element of symmetry. But it exists in two geometrical isomers which are cis and trans or fac and mer isomers.

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Which of the following does not has an optical isomer?