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Q.

Which of the following does not have optical isomers?

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a

$[Co {({NH}_{3})}_{3} {Cl}_{3}]$

b

$[Co {(en)}_{3}] {Cl}_{3}$

c

$[Co {(en)}_{2} {Cl}_{2}] Cl$

d

$[Co (en) {({NH}_{3})}_{2} {Cl}_{2}] Cl$

answer is A.

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Detailed Solution

[Co(NH₃)₃Cl₃] does not have optical isomers because, optical isomerism is shown by the type [M(AA)X₂Y₂], [M(AA)₃], [M(AA)₂X₂].

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