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Which of the following does not participate in the Solvay process for the manufacture of Na₂CO₃?

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NH₃

H₂SO₄

NaCl aq.

CO₂

answer is D.

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Detailed Solution

2NH₃ + H₂O + CO₂ → (NH₄)₂ CO₃
(NH₄)₂ CO₃ + H₂O + CO₂ → 2NH₄ CO₃
NH₄HCO₃ + NaCl → NH₄Cl + NaHCO₃↓

\large 2NaHC{O_3}\;\xrightarrow{{\;\;\Delta \;\;}}\;N{a_2}C{O_3}\; + \;C{O_2}\; + \;{H_2}O

→ Due to the low solubility of NaHCO₃, it gets precipitated in the reaction of NaCl with NH₄HCO₃ the sodium bicarbonate on calcination gives thermally stable sodium carbonate.
→ H₂SO₄ doesnot participate in the solvay's process.

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