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Q.

Which of the following elements exhibits negative oxidation state ?

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a

Sn

b

Pb

c

Ge

d

C

answer is D.

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Detailed Solution

IV A group elements
Common oxidation state is : "+4"
C shows :- +4 -4
Si:- +4 [Stable]

Ge, Sn  -  +2,+4stable        Pb: -     +2stable, +4
→ For Ge,Sn +4 is stable oxidation state hence in +2 oxidation state they acts as reducing agents
→ Where as for Pb +2 oxidation state is stable [due to inert pair effect] hence in +4 oxidation state Pb acts as oxidising agent
→ Higher oxidation state is due to involvement of ns and np electrons
i.e., 

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Lower oxidation state is due to involvent of only np electron
i.e., ns2 np(2) ⇒ +2
Higher oxidation stable stability dcecreases from top to bottom

Ge+4>Sn+4>Pb+4Stability order Ge+4<Sn+4<Pb+4Oxidising power order
Lower oxidation state  stability increases from top to bottom
Ge+2 < Sn+2 < Pb+2 : Stability order
Eg : 

Question Image


Be2C ⇒ C-4
Al4C3 ⇒ 4Al+3  3C-4

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